Welcome to Po-Heng Lin's Lab

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1. Guan-Lin Lu, Shih-Ting Chiu, Po-Heng Lin*, Jérôme Long*, “Modulating magnetic anisotropy in linear tetranuclear dysprosium(iii) complexes via coordinated anions” Dalton Trans., 2024, accepted.

2. Guan-Lin Lu, Shih-Ting Chiu, Jérôme Long*, Po-Heng Lin*, ”Fine-Tuning of Magnetic Anisotropy in Tetranuclear M2Dy2 Complexes with Zig-Zag Topology: The Impact of 3d Metal Selection” Cryst. Growth Des., 2024, accepted.

3. Nien-Chi Chang Liao, R. Sidick Basha, Bo-Hao Shih, Chia-Chun Liu, Miao-Han Wang, Po-Heng Lin*, Chin-Fa Lee,* “Copper Cluster Complex Catalyzed C-S bond Formation” Catal. Sci. Technol., 2024, DOI:10.1039/D4CY00968A 

4. Ting-Hung Chu, Wen-Qi Zeng, Li-Wei Cheng, Jason D Braun, David E Herbert, Po-Heng Lin* “Exploring the structural variations and magnetic properties of three hexanuclear dysprosium (III) complexes exhibiting single-molecule magnetism behavior” Polyhedron, 2024, 263, 117189.

5. Jin-Wei Liu, Yu-Chia Su, Chia-Chun Liu, Po-Heng Lin*, Bao-Tsan Ko “Investigation of the correlation between the substituent effect of ligands and the catalytic activity/magnetic properties in fine-tuned rare-earth complexes” Inorg. Chim. Acta., 2024, 564, 121942.

6. Amelia Kacperkiewicz, Robert J. Ortiz, Shih-Ting Chiu, Po-Heng Lin, David E. Herbert* “Towards spin-crossover in pseudo-octahedral iron(III) complexes of strongly absorbing phenanthridine-based N^N^O- ligands” Inorg. Chim. Acta., 2024, 563, 121895

7. Miao-Han Wang, Min-Yem Tsai, Yu-Chia Su, Shih-Ting Chiu, Po-Heng Lin*, Jérôme Long* “Zero-Field Single-Molecule Magnet Behavior in a Series of Dinuclear Dysprosium (III) Complexes Based on Benzothiazolyl-Based Ligands and β-Diketonates”, Cryst. Growth Des., 2024, 24, 422-431.

8. Min-Yu Wu, Jing-Xiang Xu, Yi-Hsin Chen, I‐Chung Lu, Jeng-Liang Han, Po-Heng Lin* “Self-assembled Lanthanide-based Helixes: Synthetic Control of the Helical Handedness by Chirality of the Ligand”, Dalton Trans., 2022, 51, 69-73.

9. Bo-Yi Chen, Min-Yem Tsai,  Po-Heng Lin* and Jérôme Long* “Synthesis, structures and magnetic properties of dysprosium(III) complexes based on amino-bis(benzotriazole phenolate) and nitrophenolates: influence over the slow relaxation of the magnetization”, CrystEngComm, 2021, 23, 8343-8350

10. Ching-Wei Tung, Cheng-Han Tso, Bo-Yi Chen, Hang Chu, Cheng-Hung Hou, Hsiao-Chien Chen, Mu-Chieh Chang, Jing-Jong Shyue, Po-Heng Lin* and Hao Ming Chen* “Heterocyclic-Additive-Activated Dinuclear Dysprosium Electrocatalysts for Heterogeneous Water Oxidation”, Inorg. Chem., 2021, 60, 6930-6938.

11. Li-Wei Cheng, Chi-Lung Zhang, Jun-Yu Wei and Po-Heng Lin* “Mononuclear and Trinuclear DyIII SMMs with Schiff-base Ligands Modified by Nitro- Group: First Triangular Complex with N-N Pathway”, Dalton Trans., 2019, 48, 17331-17339.

12. Yu-Chia Su, Ting-Yu Chiu, Yun-Ting Liu, Po-Heng Lin* and Bao-Tsan Ko “Significant enhancement of catalytic properties in mononuclear yttrium complexes by nitrophenolate-type ligands: synthesis, structure and catalysis for lactide polymerization” J. Polym. Sci. A Polym. Chem., 2019, 57, 2038–2047.

13. Ting-Yu Chiu, Wei Chin, Jiun-Rung Guo, Chien-Fu Liang, and Po-Heng Lin* “Dinuclear Dysprosium Complex as Air-Stable and Recyclable Catalyst: Application in Deacetylation of Carbohydrate, Aliphatic and Aromatic Molecules” Chem. Asian J., 2019, 14, 627-633.

14. Wei Chin and Po-Heng Lin* “Influence of Energy Barriers in Triangular Dysprosium Single-Molecule Magnets through Different Substitutions on a Nitrophenolate-Type Coligand” Inorg. Chem., 2018, 57, 12448-12451.

15. Paul Richardson, Ting-Jung Hsu, Che-Jung Kuo, Rebecca J. Holmberg, Bulat Gabidullin, Mathieu Rouzières, Rodolphe Clérac, * Muralee Murugesu * and Po-Heng Lin* “[Ln16] complexes (Ln = GdIII, DyIII): molecular analogues of natural minerals such as hydrotalcite” Dalton Trans., 2018, 47, 12847-12851.

16. Jun-Yu Wei, Ting-Jung Hsu, Chia-Wei Wang, Che-Jung Kuo, Po-Heng Lin*, “Alternate Synthetic Pathway Leading to Isolation of Dinuclear Single‐Molecule Magnet” Eur. J. Inorg. Chem., 2018, 2018, 3397-3401.

17. Chia-Hsing Ho, Hui-Ju Chuang, Po-Heng Lin*, Bao-Tsan Ko, “Copolymerization of Carbon Dioxide with Cyclohexene Oxide Catalyzed by Bimetallic Dysprosium Complexes Containing Hydrazine Functionalized Schiff-Base Derivatives” J. Polym. Sci. A Polym. Chem., 2017, 55, 321–328.

18. Rebecca J. Holmberg, Che-Jung Kuo, Bulat Gabidullin, Chia-Wei Wang, Rodolphe Clérac,* Muralee Murugesu* and Po-Heng Lin*, “A propeller-shaped μ4-carbonate hexanuclear dysprosium complex with a high energetic barrier to magnetisation relaxation” Dalton Trans., 2016, 45, 16769-16773.

19. Kuan-Chin Lee, Hui-Ju Chuang, Bor-Hunn Huang, Bao-Tsan Ko, Po-Heng Lin*, “Structurally diverse dysprosium and yttrium complexes containing an amine-bis(benzotriazole phenolate) ligand: Synthesis, characterization and catalysis for lactide polymerization.” Inorg. Chim. Acta., 2016, 450, 411–417

20. Po-Heng Lin, Emily Y. Tsui, Fatemah Habib, Muralee Murugesu,* and Theodor Agapie*, “Effect of the Mn Oxidation State on Single-Molecule-Magnet Properties: MnIII vs MnIV in Biologically Inspired DyMn3O4 Cubanes.” Inorg. Chem., 2016, 55, 6095.

21. Che-Jung Kuo, Rebecca J. Holmberg, Po-Heng Lin*, “Slight Synthetic Changes Eliciting Different Topologies: Synthesis, Structure and Magnetic Properties of Novel Dinuclear and Nonanuclear Dysprosium Complexes.” Dalton Trans., 2015, 44, 19758.

22. Po-Heng Lin, Michael K. Takase, Theodor Agapie*, “Investigations of the Effect of the Non-Manganese Metal in Heterometallic-OxidoCluster Models of the Oxygen Evolving Complex of Photosystem II: Lanthanides as Substitutes for Calcium.” Inorg. Chem., 2015, 54, 59. 

23. Jacob S. Kanady, Po-Heng Lin, Kurtis M. Carsch, Robert J. Nielsen, Michael K. Takase, William A. Goddard, III, Theodor Agapie, “Toward Models for the Full Oxygen-Evolving Complex of Photosystem II by Ligand Coordination To Lower the Symmetry of the Mn3CaO4Cubane: Demonstration That Electronic Effects Facilitate Binding of a Fifth Metal” J. Am. Chem. Soc., 2014, 136, 14373.

24.  Jianguo Wu, Gray W. Brudvig, Wei Dai, Louise M. Guard, Nilay Hazari*, Po-Heng Lin, Ravi Pokhrel and Michael K. Takase, “Nickel(I) Monomers and Dimers with Cyclopentadienyl and Indenyl Ligands.” Chem. Eur. J., 2014, 20, 5327.

25.  Wen-Bin Sun, Bing-Lu Han, Po-Heng Lin, Hong-Feng Li, Peng Chen, Yong-Mei Tian, Muralee, Murugesu* and Peng-Fei Yan*, “Series ofDinuclear and Tetranuclear Lanthanide Clusters Encapsulated by Salen-Type and β-Diketionate Lignads: Single-Molecule Magnet and Fluorescence Properties.” Dalton Trans., 2013, 42, 13397.

26. Po-Heng Lin, Ilia Korobkov, Tara J. Burchell, Muralee Murugesu,* “Connecting Single-Ion Magnets through Ligand Dimerisation.” Dalton Trans., 2012, 41, 13649.

27. Po-Heng Lin, Wen-Bin Sun,* Yong-Mei Tian, Peng-Fei Yan,* Liviu Ungur, Liviu F. Chibotaru,* Muralee Murugesu,* “Ytterbium can relax slowly too: a field-induced Yb2 single-molecule magnet.” Dalton Trans., 2012, 41, 12349.

28. Fatemah Habib, Jérôme Long, Po-Heng Lin, Ilia Korobkov, Liviu Ungur, Liviu F. Chibotaru, Muralee Murugesu,* “Supramolecular architectures for controlling slow magnetic relaxation in field-induced single-molecule magnets.” Chem. Sci., 2012, 3, 2158.

29. R. Thomas Baker*, John C. Gordon*, Charles W. Hamilton, Neil J. Henson, Po-Heng Lin, Muralee Murugesu, Brian L. Scott and Nathan C.Smythe, “Iron Complex-Catalyzed Ammonia-Borane Dehydrogenation. A Potential Route towards B-N Containing Polymer Motifs Using Earth Abundant Metal Catalysts.” J. Am. Chem. Soc., 2012, 134, 5598.

30. Matthew Jeletic, Po-Heng Lin, Jennifer J. Le Roy, Ilia Korobkov, Muralee Murugesu,* “An Organometallic Sandwich Lanthanide Single-Molecule Magnet with an Unusual Multiple Relaxation Mechanism.” J. Am. Chem. Soc., 2011, 133, 19286.

31. Po-Heng Lin, Nathan C. Smythe, Serge Gorelsky, Steven Maguire, Neil J. Henson, Ilia Korobkov, Brian L. Scott, John C. Gordon, R. Tom Baker,Muralee Murugesu*, “Importance of Out-of-State Spin-Orbit Coupling for Slow Magnetic Relaxation in Mono-nuclear FeII complexes.” J. Am. Chem. Soc., 2011, 133, 15806.

32. Titel Jurca, Ahmed Farghal, Po-Heng Lin, Ilia Korobkov, Muralee Murugesu*, Darrin S. Richeson,* “Single-Molecule Magnet Behavior with a Single Metal Center Enhanced through Peripheral Ligand Modifications” J. Am. Chem. Soc., 2011, 133, 15814.

33. Po-Heng Lin, Wen-Bin Sun,* Mang-Fei Yu, Guang-Ming Li, and Peng-Fei Yan,* Muralee Murugesu,* “An Unsymmetrical Coordination Environment Leading to Two Slow Relaxation Modes in Dy2 Single-Molecule Magnet.” Chem. Commun., 2011, 47, 10993.

34. Peng-Fei Yan, Po-Heng Lin, Fatemah Habib, Tomoko Aharen, Muralee Murugesu,* Zhao-Peng Deng, Guang-Ming Li, Wen-Bin Sun*, “PlanarTetranuclear Dy(III) Single-Molecule Magnet and Its Sm(III), Gd(III) and Tb(III) Analogues Encapsulated By Salen-Type and β-DiketonateLigands.” Inorg. Chem., 2011, 50, 7059.

35. Po-Heng Lin, Sarah Eastman, Aman Bhatti, Melanie Brulotte, Tara J. Burchell, Ilia Korobkov, Gary Enright, Rodolphe Clérac and MuraleeMurugesu*, “Polyalcohol Ligands in CuII and FeIII Cluster Chemistry: Synthesis, Structures and Magnetic Properties of {Cu12} and {Fe8} Aggregates.” Inorg. Chim. Acta., 2011, 375, 187.

36.  Fatemah Habib, Po-Heng Lin, Jérôme Long, Ilia Korobkov, Wolfgang Wernsdorfer and Muralee Murugesu*, “The Use of Magnetic Dilution to Elucidate the Slow Magnetic Relaxation Effects of a Dy2 Single-Molecule Magnet” J. Am. Chem. Soc., 2011, 133, 8830.

37. Derek J. Reid, John E. W. Cull, Kimberley D. S. Chisholm, Alexandre Langlois, Po-Heng Lin, Jérôme Long, Olivier Lebel, Ilia Korobkov, RuiyaoWang, James D. Wuest, Muralee Murugesu and Jennifer Scott*, “Synthesis, Structure and Magnetism of Homodinuclear Complexes of Co, Ni and Cu Supported by a Novel Bitriazine Scaffold.” Dalton Trans., 2011, 40, 5009.

38. Po-Heng Lin, Ilia Korobkov, Wolfgang Wernsdorfer, Liviu Ungur, Liviu F. Chibotaru and Muralee Murugesu*, “A Rare μ4-O Centred Dy4Tetrahedron with Coordination-Induced Local Chirality and Single-Molecule Magnet Behaviour.” Eur. J. Inorg. Chem., 2011, 2011, 1535.

39. Jérôme Long, Fatemah Habib, Po-Heng Lin, Ilia Korobkov, Gary Enright, Liviu Ungur, Wolfgang Wernsdorfer, Liviu F. Chibotaru  and MuraleeMurugesu*, “Single-Molecule Magnet Behavior for an Antiferromagnetically Superexchange-Coupled a Dinuclear Dysprosium(III) Complex.” J. Am. Chem. Soc., 2011, 133, 5319.

40. Po-Heng Lin, Serge Gorelsky, Didier Savard, Tara J. Burchell, Wolfgang Wernsdorfer, Rodolphe Clérac and Muralee Murugesu*, “Synthesis,Characterisation and Computational Studies on a Novel One-Dimensional Arrangement of Schiff-base Mn3 Single-Molecule Magnet.” Dalton Trans., 2010, 39, 7650. (CrystEngSelects from across the RSC journals.

41. Po-Heng Lin, Mathieu Leclère, Jérôme Long, Tara J. Burchell, Ilia Korobkov, Rodolphe Clérac and Muralee Murugesu*, “FluorescentDialdehyde Ligand for the Encapsulation of Dinuclear Luminescent Lanthanide Complexes.” Dalton Trans., 2010, 39, 5698.

42. Po-Heng Lin, Tara J. Burchell, Liviu Ungur, Liviu Chibotaru, Wolfgang Wernsdorfer and Muralee Murugesu*, “A Polynuclear Lanthanide Single-Molecule Magnet with a Record Anisotropic Barrier.” Angew. Chem. Int. Ed., 2009, 48, 9489.

43. Didier Savard, Po-Heng Lin, Tara J. Burchell, Wolfgang Wernsdorfer, Rodolphe Clérac and Muralee Murugesu*, “Two-Dimensional Networks of Lanthanide Cubane-Shaped Dumbbells.” Inorg. Chem., 2009, 48, 11748.

44. Carolyn E. Burrow, Tara J. Burchell, Po-Heng Lin, Fatemah Habib, Wolfgang Wernsdorfer, Rodolphe Clérac and Muralee Murugesu* , “Salen-Based [Zn2Ln3] Complexes with Fluorescence and Single Molecule Magnet Properties,” Inorg. Chem., 2009, 48, 8051.

45. Po-Heng Lin, Tara J. Burchell, Rodolphe Clérac* and Muralee Murugesu*, “Dinuclear Dysprosium(III) Single-Molecule Magnets with a Large Anisotropic Barrier.” Angew. Chem. Int. Ed., 2008, 47, 8848.